The specific hybridization states of carbon atoms shape diamond and graphite
two well-known allotropes. Under specific conditions
diamond undergoes graphitization
resulting in distinct microstructural and macroscopic property changes. The graphitization of diamond has emerged as a core technology in many application-driven fields. This paper comprehensively reviewed studies on diamond graphitization across various domains to address urgent demands in these industries and the forthcoming semiconductor revolution. Beginning with the definition of diamond graphitization
the article explored its manifestations
thermodynamic and kinetic mechanisms
and influencing factors. The research on diamond graphitization was divided into three stages
focusing on fields such as heating/heat treatment
diamond tools/coatings
irradiation/ion implantation
dissolution/chemical etching
polishing
and simulation/emulation. The key distinctions between graphitization
amorphization
and oxidation were clarified
and the effects of temperature
pressure
atmosphere
and processing parameters on graphitization were summarized. The article introduced the functional application technology from the perspective of utilizing or suppressing diamond graphitization
followed by prospects for future developments in the field of diamond graphitization research.