1. a Key Laboratory of Marine Materials and Related Technologies Zhejiang Key Laboratory of Marine Materials and Protective Technologies Ningbo Institute of Materials Technology and Engineering (NIMTE) Chinese Academy of Sciences Ningbo P.R. China
2. b Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences
3. c State Key Laboratory of Intense Pulsed Radiation Simulation and Effect Northwest Institute of Nuclear Technology
4. d School of Electronics and Information Engineering Ningbo University of Technology
5. a Key Laboratory of Marine Materials and Related Technologies Zhejiang Key Laboratory of Marine Materials and Protective Technologies Ningbo Institute of Materials Technology and Engineering (NIMTE) Chinese Academy of Sciences
6. e Mechanical Systems Engineering Kogakuin University
7. f Hefei National Laboratory for Physical Sciences at Microscale Department of Physics University of Science and Technology of China Hefei P.R. China
8. g Laser Research Institute Shandong Academy of Sciences
9. h Ningbo Institute of Materials Technology and Engineering (NIMTE) Chinese Academy of Sciences
网络首发:2022-08-24,
纸质出版:2022
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Qilong Yuan, Linyue Liu, Dan Dai, 等. A single-crystalline diamond X-ray detector based on direct sp3-to-sp2 conversed graphene electrodes[J]. Functional Diamond, 2022,2(1):94-102.
Qilong Yuan, Linyue Liu, Dan Dai, et al. A single-crystalline diamond X-ray detector based on direct sp3-to-sp2 conversed graphene electrodes[J]. Functional Diamond2022, 2(1): 94-102.
Qilong Yuan, Linyue Liu, Dan Dai, 等. A single-crystalline diamond X-ray detector based on direct sp3-to-sp2 conversed graphene electrodes[J]. Functional Diamond, 2022,2(1):94-102. DOI: 10.1080/26941112.2022.2099766.
Qilong Yuan, Linyue Liu, Dan Dai, et al. A single-crystalline diamond X-ray detector based on direct sp3-to-sp2 conversed graphene electrodes[J]. Functional Diamond2022, 2(1): 94-102. DOI: 10.1080/26941112.2022.2099766.
Diamond is an ultrawide bandgap semiconductor with excellent electronic and photonic properties
which has great potential applications in microelectronic and optoelectronic devices. As an allotrope of diamond
graphene also has many fantastic properties like diamond
which caught much attention in combing them together. In this work
a direct sp
3
-to-sp
2
conversion method was proposed to fabricate graphene layers on single crystal diamond by thermal treatment with Ni film catalyst. By optimizing the conversing conditions
a thin graphene layer with low sheet resistance was obtained on diamond. Based on this
an all-carbon sandwich structural graphene-diamond-graphene (GDG) detector was fabricated
which shows low dark current of 0.45 nA at 0.5 V μm
−1
applied electric field. The maximum sensitivity of this detector is obtained when the incident X-ray is 12 keV
with the value of 2.88 × 10
−8
C Gy
−1
. Moreover
the rise time and delay time of the GDG detector is about 1.2 and 22.8 ns
respectively
which are very close to that of diamond detector with Ti/Au electrode. The realization of the direct
in-situ
sp
3
-to-sp
2
conversion on diamond shows a promising approach for fabricating diamond-based all-carbon electronic devices.
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