Research on controllable ozone oxidation on diamond surface

Tao Qiu; Meihua Liu; Tangbangguo Zhou; Xu Lin; Bin Xu

doi:10.1080/26941112.2022.2098064

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Research on controllable ozone oxidation on diamond surface

Research Article | Updated：2022-08-16

- Research on controllable ozone oxidation on diamond surface
- Research on controllable ozone oxidation on diamond surface
- Functional Diamond 2022年2卷第1期页码：84-93
- Affiliations：
  
  School of Materials Science and Engineering Central South University
- Author bio：
- Funds：
- DOI：10.1080/26941112.2022.2098064
  中图分类号：
- 网络首发：2022-08-16，
  
  纸质出版：2022
- Accepted：
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Tao Qiu, Meihua Liu, Tangbangguo Zhou, 等. Research on controllable ozone oxidation on diamond surface[J]. Functional Diamond, 2022,2(1):84-93.

Tao Qiu, Meihua Liu, Tangbangguo Zhou, et al. Research on controllable ozone oxidation on diamond surface[J]. Functional Diamond2022, 2(1): 84-93.
Tao Qiu, Meihua Liu, Tangbangguo Zhou, 等. Research on controllable ozone oxidation on diamond surface[J]. Functional Diamond, 2022,2(1):84-93. DOI： 10.1080/26941112.2022.2098064.

Tao Qiu, Meihua Liu, Tangbangguo Zhou, et al. Research on controllable ozone oxidation on diamond surface[J]. Functional Diamond2022, 2(1): 84-93. DOI： 10.1080/26941112.2022.2098064.

摘要

Abstract

In recent years

there have been more and more researches on the surface modification of diamonds

however

the exact types and quantities of oxygen-related species on diamond surfaces and the method to control the condition parameters to obtain as many oxygen-containing groups as possible have been rarely studied so far. Therefore

in this work

we focused on these questions. And we find out that ozone oxidation would not affect the overall crystal structure and morphology of diamonds. Besides

changing oxidation time and ozone concentration would significantly influence the density of hydroxyl groups

which is manifested as a change of oxygen content. In order to make the hydroxyl density on diamond surface reach a high level (3.12 × 10

units/cm

)

so that diamonds can be better combined with the resin matrix

the ozone oxidation time should be 15 min

and the ozone concentration should be 115 g•m

−3

. And under these conditions

the thermal conductivity of diamond and polysiloxane composites can reach 8.02 W/mK.

关键词

Keywords

references

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