Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability

Ruitong Zhu; Fangmu Liu; Zejun Deng; Yuhang Yu; Li Ma; Hangyu Long; Kechao Zhou; Zhiming Yu; Qiuping Wei

doi:10.1080/26941112.2022.2078168

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Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability

Research Article | Updated：2022-07-23

- Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability
- Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability
- Functional Diamond 2022年2卷第1期页码：71-79
- Affiliations：
  
  1. a State Key Laboratory of Powder Metallurgy School of Materials Science and Engineering Central South University
  2. b School of Materials Science and Engineering Central South University
  3. c School of Materials Science and Hydrogen Energy Foshan University Foshan PR China
  4. d Guangdong Provincial Key Laboratory of Modern Surface Engineering Technology Institute of New Materials Guangdong Academy of Science
- Author bio：
- Funds：
- DOI：10.1080/26941112.2022.2078168
  中图分类号：
- 网络首发：2022-07-23，
  
  纸质出版：2022
- Accepted：
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Ruitong Zhu, Fangmu Liu, Zejun Deng, 等. Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability[J]. Functional Diamond, 2022,2(1):71-79.

Ruitong Zhu, Fangmu Liu, Zejun Deng, et al. Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability[J]. Functional Diamond2022, 2(1): 71-79.
Ruitong Zhu, Fangmu Liu, Zejun Deng, 等. Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability[J]. Functional Diamond, 2022,2(1):71-79. DOI： 10.1080/26941112.2022.2078168.

Ruitong Zhu, Fangmu Liu, Zejun Deng, et al. Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability[J]. Functional Diamond2022, 2(1): 71-79. DOI： 10.1080/26941112.2022.2078168.

摘要

Abstract

Ferri/ferro-cyanide ([Fe(CN)

]

3−/4−

) redox couple has been extensively used as a benchmark to assess electrocatalytic degradation capability of boron-doped diamond (BDD) electrodes. However

the [Fe(CN)

]

3−/4−

is far more sensitive to the surface terminal groups of BDD surface than the other factors (e.g. surface morphology and electrode configuration) that are closely related to electrocatalytic degradation properties. Thus

inconsistency exists while correlating the degradation properties of BDD with electrochemical properties determined from ferri/ferro-cyanide redox couple. Herein

an exemplar pollutant

reactive blue 19 (RB-19)

was electrochemically degraded using various terminated BDD electrodes

including hydrogen-terminated (H-BDD)

oxygen-terminated (O-BDD) and porous oxygen-terminated BDDs (OE-BDD)

obtained

via

cathodic and anodic polarization as well as oxygen plasma etching

respectively. Surprisingly

OE-BDD with the lower heterogeneous electron transfer rate constant for [Fe(CN)

]

3−/4−

showed a better electrocatalytic degradation capabilit

y toward RB-19

indicating the inconsistency for qualitatively evaluating degradation properties according to the kinetic parameters extracted from [Fe(CN)

]

3−/4−

redox system.

关键词

Keywords

references

Yang N, Yu S, Macpherson JV, et al. Conductive diamond: synthesis, properties, and electrochemical applications. Chem Soc Rev. 2019;48(1):157–204. doi:10.1039/c7cs00757d PubMed Web of Science ®Google Scholar

Chen X, Zhang W. Diamond nanostructures for drug delivery, bioimaging, and biosensing. Chem Soc Rev. 2017;46(3):734–760. doi:10.1039/c6cs00109b PubMed Web of Science ®Google Scholar

Baluchová S, Daňhel A, Dejmková H, et al. Recent progress in the applications of boron doped diamond electrodes in electroanalysis of organic compounds and biomolecules: a review. Anal Chim Acta. 2019;1077:30–66. doi:10.1016/j.aca.2019.05.041 PubMed Web of Science ®Google Scholar

Deng Z, Long H, Wang Y, et al. Template-free synthesis of millimeter-scale carbon nanorod arrays on boron-doped diamond with superior glucose sensing performance. Appl Surf Sci. 2022;572:151468. doi:10.1016/j.apsusc.2021.151468 Web of Science ®Google Scholar

Li H, Zhou K, Cao J, et al. A novel modification to boron-doped diamond electrode for enhanced, selective detection of dopamine in human serum. Carbon. 2021;171:16–28. doi:10.1016/j.carbon.2020.08.019 Web of Science ®Google Scholar

Deng Z, Long H, Wei Q, et al. High-performance non-enzymatic glucose sensor based on nickel-microcrystalline graphite-boron doped diamond complex electrode. Sens Actuat BChem. 2017;242:825–834. doi:10.1016/j.snb.2016.09.176 Web of Science ®Google Scholar

Baluchova S, Taylor A, Mortet V, et al. Porous boron doped diamond for dopamine sensing: effect of boron doping level on morphology and electrochemical performance. Electrochim Acta. 2019;327:135025. doi:10.1016/j.electacta.2019.135025 Web of Science ®Google Scholar

Holt KB, Bard AJ, Show Y, et al. Scanning electrochemical microscopy and conductive probe atomic force microscopy studies of hydrogen-terminated boron-doped diamond electrodes with different doping levels. J Phys Chem B. 2004;108(39):15117–15127. doi:10.1021/jp048222x Web of Science ®Google Scholar

Garcia-Segura S, Vieira dos Santos E, Martínez-Huitle CA. Role of sp(3)/sp(2) ratio on the electrocatalytic properties of boron-doped diamond electrodes: a mini review. Electrochem Commun. 2015;59:52–55. doi:10.1016/j.elecom.2015.07.002 Web of Science ®Google Scholar

Chaplin BP. Critical review of electrochemical advanced oxidation processes for water treatment applications. Environ Sci Process Impacts. 2014;16(6):1182–1203. doi:10.1039/c3em00679d PubMed Web of Science ®Google Scholar

Liu Z, Li H, Li M, et al. Preparation of polycrystalline BDD/ta electrodes for electrochemical oxidation of organic matter. Electrochim Acta. 2018;290:109–117. doi:10.1016/j.electacta.2018.09.058 Web of Science ®Google Scholar

Li X, Li H, Li M, et al. Preparation of a porous boron-doped diamond/ta electrode for the electrocatalytic degradation of organic pollutants. Carbon. 2018;129:543–551. doi:10.1016/j.carbon.2017.12.052 Web of Science ®Google Scholar

Wang H, Sayed SY, Luber EJ, et al. Redox flow batteries: how to determine electrochemical kinetic parameters. ACS Nano. 2020;14(3):2575–2584. doi:10.1021/acsnano.0c01281 PubMed Web of Science ®Google Scholar

Lavagnini I, Antiochia R, Magno F. An extended method for the practical evaluation of the standard rate constant from cyclic voltammetric data. Electroanalysis. 2004;16(6):505–506. doi:10.1002/elan.200302851 Web of Science ®Google Scholar

Miao D, Liu T, Yu Y, et al. Study on degradation performance and stability of high temperature etching boron-doped diamond electrode. Appl Surf Sci. 2020;514:146091. doi:10.1016/j.apsusc.2020.146091 Web of Science ®Google Scholar

Mei R, Wei Q, Zhu C, et al. 3D macroporous boron-doped diamond electrode with interconnected liquid flow channels: a high-efficiency electrochemical degradation of RB-19 dye wastewater under low current. Appl Catal B Environ. 2019;245:420–427. doi:10.1016/j.apcatb.2018.12.074 Web of Science ®Google Scholar

Hutton LA, Iacobini JG, Bitziou E, et al. Examination of the factors affecting the electrochemical performance of oxygen-terminated polycrystalline boron-doped diamond electrodes. Anal Chem. 2013;85(15):7230–7240. doi:10.1021/ac401042t PubMed Web of Science ®Google Scholar

Salazar-Banda GR, Andrade LS, Nascente PAP, et al. On the changing electrochemical behaviour of boron-doped diamond surfaces with time after cathodic pre-treatments. Electrochim Acta. 2006;51(22):4612–4619. doi:10.1016/j.electacta.2005.12.039 Web of Science ®Google Scholar

Macpherson JV. A practical guide to using boron doped diamond in electrochemical research. Phys Chem Chem Phys. 2015;17(5):2935–2949. doi:10.1039/c4cp04022h PubMed Web of Science ®Google Scholar

Kamoshida N, Kasahara S, Ikemiya N, et al. In situ ATR-IR study of Fe(CN)(6)(3-)/Fe(CN)(6)(4-) redox system on boron-doped diamond electrode. Diamond Relat Mater. 2019;93:50–53. doi:10.1016/j.diamond.2019.01.021 Web of Science ®Google Scholar

Liu F, Deng Z, Miao D, et al. A highly stable microporous boron-doped diamond electrode etched by oxygen plasma for enhanced electrochemical ozone generation. J Environ Chem Eng. 2021;9(6):106369. doi:10.1016/j.jece.2021.106369 Web of Science ®Google Scholar

Mei R, Zhu C, Wei Q, et al. The dependence of oxidation parameters and dyes’ molecular structures on microstructure of boron-doped diamond in electrochemical oxidation process of dye wastewater. J Electrochem Soc. 2018;165(7):H324–H332. doi:10.1149/2.0221807jes Web of Science ®Google Scholar

Zhou B, Yu Z, Wei Q, et al. Electrochemical oxidation of biological pretreated and membrane separated landfill leachate concentrates on boron doped diamond anode. Appl Surf Sci. 2016;377:406–415. doi:10.1016/j.apsusc.2016.03.045 Web of Science ®Google Scholar

Kang X, Zhang Z, Gou L. Improvement in electrical conductivity of boron-doped diamond films after hydrogen plasma and vacuum heat treatment. Appl Surf Sci. 2020;526:146738. doi:10.1016/j.apsusc.2020.146738 Web of Science ®Google Scholar

Liu D, Gou L, Xu J, et al. Investigations on etching resistance of undoped and boron doped polycrystalline diamond films by oxygen plasma etching. Vacuum. 2016;128:80–84. doi:10.1016/j.vacuum.2016.03.012 Web of Science ®Google Scholar

Li H, Guo Y, Zeng S, et al. High-sensitivity, selective determination of dopamine using bimetallic nanoparticles modified boron-doped diamond electrode with anodic polarization treatment. J Mater Sci. 2021;56(7):4700–4715. doi:10.1007/s10853-020-05577-4 Web of Science ®Google Scholar

May PW, Ludlow WJ, Hannaway M, et al. Raman and conductivity studies of boron-doped microcrystalline diamond, facetted nanocrystalline diamond and cauliflower diamond films. Diamond Relat Mater. 2008;17(2):105–117. doi:10.1016/j.diamond.2007.11.005 Web of Science ®Google Scholar

Kasahara S, Natsui K, Watanabe T, et al. Surface hydrogenation of boron-doped diamond electrodes by cathodic reduction. Anal Chem. 2017;89(21):11341–11347. doi:10.1021/acs.analchem.7b02129 PubMed Web of Science ®Google Scholar

Campos-Roldán CA, Ramos-Sánchez G, Gonzalez-Huerta RG, et al. Influence of sp3–sp2 carbon nanodomains on metal/support interaction, catalyst durability, and catalytic activity for the oxygen reduction reaction. ACS Appl Mater Interfaces. 2016;8(35):23260–23269. doi:10.1021/acsami.6b06886 PubMed Web of Science ®Google Scholar

Ayres ZJ, Borrill AJ, Newland JC, et al. Controlled sp2 functionalization of boron doped diamond as a route for the fabrication of robust and nernstian pH electrodes. Anal Chem. 2016;88(1):974–980. doi:10.1021/acs.analchem.5b03732 PubMed Web of Science ®Google Scholar

Ryl J, Burczyk L, Bogdanowicz R, et al. Study on surface termination of boron-doped diamond electrodes under anodic polarization in H2SO4 by means of dynamic impedance technique. Carbon. 2016;96:1093–1105. doi:10.1016/j.carbon.2015.10.064 Web of Science ®Google Scholar

Yagi I, Notsu H, Kondo T, et al. Electrochemical selectivity for redox systems at oxygen-terminated diamond electrodes. J Electroanal Chem. 1999;473(1-2):173–178. doi:10.1016/s0022-0728(99)00027-3 Web of Science ®Google Scholar

Ostrovskaya L, Perevertailo V, Ralchenko V, et al. Wettability and surface energy of oxidized and hydrogen plasma-treated diamond films. Diamond Relat Mater. 2002;11(3-6):845–850. doi:10.1016/s0925-9635(01)00636-7 Web of Science ®Google Scholar

Fan J, Shi H, Xiao H, et al. Double-layer 3D macro–mesoporous metal oxide modified boron-doped diamond with enhanced photoelectrochemical performance. ACS Appl Mater Interfaces. 2016;8(42):28306–28315. doi:10.1021/acsami.6b01929 PubMed Web of Science ®Google Scholar

Li H, Yang W, Ma L, et al. 3D-printed highly ordered Ti networks-based boron-doped diamond: an unprecedented robust electrochemical oxidation anode for decomposition of refractory organics. Chem Eng J. 2021;426:131479. doi:10.1016/j.cej.2021.131479 Web of Science ®Google Scholar

Randviir EP. A cross examination of electron transfer rate constants for carbon screen-printed electrodes using electrochemical impedance spectroscopy and cyclic voltammetry. Electrochim Acta. 2018;286:179–186. doi:10.1016/j.electacta.2018.08.021 Web of Science ®Google Scholar

Futera Z, Watanabe T, Einaga Y, et al. First principles calculation study on surfaces and water interfaces of boron-doped diamond. J Phys Chem C. 2014;118(38):22040–22052. DOI:10.1021/jp506046m Web of Science ®Google Scholar

Lombardi EB. Boron–hydrogen complexes in diamond and their vibrational properties. Diamond Relat Mater. 2009;18(5-8):835–838. doi:10.1016/j.diamond.2009.01.022 Web of Science ®Google Scholar

Chen C, Nurhayati E, Juang Y, et al. Electrochemical decolorization of dye wastewater by surface-activated boron-doped nanocrystalline diamond electrode. J Environ Sci. 2016;45:100–107. doi:10.1016/j.jes.2016.01.004 Google Scholar

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