1. a Materials Science and Engineering and Bioengineering University of Texas at Dallas Richardson Texas USA
2. b Co-founder (Advanced Diamond Technologies Inc sold in 2019) Lemont IL USA
3. c Original Biomedical Implants (OBI-USA) Richardson TX USA
4. d Original Biomedical Implants (OBI-México),Hermosillo
网络首发:2022-02-22,
纸质出版:2022
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Orlando Auciello. Science and technology of a transformational multifunctional ultrananocrystalline diamond (UNCDTM) coating[J]. Functional Diamond, 2022,2(1):1-24.
Orlando Auciello. Science and technology of a transformational multifunctional ultrananocrystalline diamond (UNCDTM) coating[J]. Functional Diamond2022, 2(1): 1-24.
Orlando Auciello. Science and technology of a transformational multifunctional ultrananocrystalline diamond (UNCDTM) coating[J]. Functional Diamond, 2022,2(1):1-24. DOI: 10.1080/26941112.2022.2033606.
Orlando Auciello. Science and technology of a transformational multifunctional ultrananocrystalline diamond (UNCDTM) coating[J]. Functional Diamond2022, 2(1): 1-24. DOI: 10.1080/26941112.2022.2033606.
This review focuses on describing the fundamental/applied materials science and technological applications of a transformational multifunctional diamond-based material named ultrananocrytalline diamond (UNCD
TM
) in film form. The UNCD
TM
films are synthesized using microwave plasma chemical vapor deposition (MPCVD) and hot filament chemical vapor deposition (HFCVD)
via
patented Ar/CH
4
gas flown into air evacuated chambers
using microwave power
or hot filaments’ surface
to crack CH
4
molecules to generate C atoms and CHx (
x
= 1
2
3) species
which produce chemical reactions on substrates’ surfaces
producing diamond film with grain sizes in the range 3–5 nm (smallest grain size known today for any polycrystalline diamond film)
providing the bases for the name UNCD. UNCD coatings exhibit a unique combination of properties
namely: (1) super high hardness and Young modulus
similar to the crystal gem of diamond; (2) lowest coefficient of friction compared to other diamond or diamond-like coatings; (3) no mechanical surface wear; (4) highest resistance to chemical attach by any corrosive fluid; (5) only
diamond film exhibiting electrical conductivity
via
Nitrogen inserted in grain boundaries
binding to C atoms and providing electrons for electrical conduction
or B atoms substituting C atoms in the diamond lattice
providing electrons to the conduction band; and (6) best biocompatibility
since UNCD coatings are formed by C atoms (element of life in human DNA
cells/molecules). The UNCD films’ properties provide unique multifunctionalities
enabling new generations of industrial
electronic
high-tech
and implantable medical devices/prostheses
enabling substantial improvement in the way and quality of life of people worldwide.
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