

FOLLOWUS
1. a National Key Laboratory of Special Environment Composite Technology Harbin Institute of Technology
2. b School of Chemistry and Chemical Engineering Beijing Institute of Technology
3. c HRG Institute (Zhongshan) of Unmanned Equipment & AI
4. a National Key Laboratory of Special Environment Composite Technology Harbin Institute of Technology Harbin China
5. d Key Laboratory of Micro-systems and Micro-structures Manufacturing Ministry of Education Harbin Institute of Technology
Online First:05 January 2023,
Published:2022
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Weihua Wang, Benjian Liu, Leining Zhang, et al. Heteroepitaxy of diamond semiconductor on iridium: a review[J]. Functional Diamond2022, 2(1): 215-235.
Weihua Wang, Benjian Liu, Leining Zhang, et al. Heteroepitaxy of diamond semiconductor on iridium: a review[J]. Functional Diamond2022, 2(1): 215-235. DOI: 10.1080/26941112.2022.2162348.
one of the representatives of carbon-based semiconductors
diamond is called the “Mount Everest” of electronic materials. To maximize its properties and realize its industrial applications
the fabrication of wafer-scale high-quality diamonds is critical. To date
heteroepitaxy is considered as a promising method for the growth of diamond wafers with considerable development. In this review
fundamentals of diamond heteroepitaxy is firstly introduced from several perspectives including nucleation thermodynamics and kinetic
nucleation process at the atomic level
as well as the interplay between the epitaxial film and substrate. Second
the bias enhanced nucleation (BEN) method is reviewed
including BEN setup
BEN process window
nucleation phenomenology (mainly on Iridium)
nucleation mechanism by ion bombardment
and large-scale nucleation realization. Third
the following textured growth process is presented
as well as grain boundary annihilation
and dislocation and stress reduction technologies. Fourth
the applications of diamonds in electronic devices are studied
showing its excellent performances in the future power and electronic devices. Finally
prospects in this field are proposed from several aspects.
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