Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability

Ruitong Zhu; Fangmu Liu; Zejun Deng; Yuhang Yu; Li Ma; Hangyu Long; Kechao Zhou; Zhiming Yu; Qiuping Wei

doi:10.1080/26941112.2022.2078168

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Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability

Research Article | Updated：2022-07-23

- Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability
- Functional Diamond Vol. 2, Issue 1, Pages: 71-79(2022)
- Affiliations：
  
  1. a State Key Laboratory of Powder Metallurgy School of Materials Science and Engineering Central South University
  2. b School of Materials Science and Engineering Central South University
  3. c School of Materials Science and Hydrogen Energy Foshan University Foshan PR China
  4. d Guangdong Provincial Key Laboratory of Modern Surface Engineering Technology Institute of New Materials Guangdong Academy of Science
- Author bio：
- Funds：
- DOI：10.1080/26941112.2022.2078168
  CLC：
- Online First：23 July 2022，
  
  Published：2022
- Accepted：
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Ruitong Zhu, Fangmu Liu, Zejun Deng, et al. Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability[J]. Functional Diamond2022, 2(1): 71-79.
DOI：

Ruitong Zhu, Fangmu Liu, Zejun Deng, et al. Inconsistency of BDD reactivity assessed by ferri/ferro-cyanide redox system and electrocatalytic degradation capability[J]. Functional Diamond2022, 2(1): 71-79. DOI： 10.1080/26941112.2022.2078168.

摘要

Abstract

Ferri/ferro-cyanide ([Fe(CN)

]

3−/4−

) redox couple has been extensively used as a benchmark to assess electrocatalytic degradation capability of boron-doped diamond (BDD) electrodes. However

the [Fe(CN)

]

3−/4−

is far more sensitive to the surface terminal groups of BDD surface than the other factors (e.g. surface morphology and electrode configuration) that are closely related to electrocatalytic degradation properties. Thus

inconsistency exists while correlating the degradation properties of BDD with electrochemical properties determined from ferri/ferro-cyanide redox couple. Herein

an exemplar pollutant

reactive blue 19 (RB-19)

was electrochemically degraded using various terminated BDD electrodes

including hydrogen-terminated (H-BDD)

oxygen-terminated (O-BDD) and porous oxygen-terminated BDDs (OE-BDD)

obtained

via

cathodic and anodic polarization as well as oxygen plasma etching

respectively. Surprisingly

OE-BDD with the lower heterogeneous electron transfer rate constant for [Fe(CN)

]

3−/4−

showed a better electrocatalytic degradation capabilit

y toward RB-19

indicating the inconsistency for qualitatively evaluating degradation properties according to the kinetic parameters extracted from [Fe(CN)

]

3−/4−

redox system.

关键词

Keywords

references

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